Pyrargyrite is an interesting mineral that contains silver in its chemical structure. It is one of the few silver-bearing minerals that can exhibit transparency. Pyrargyrite contains two very distinct habits: as transparent, deep-red crystals, and in opaque, dark-metallic gray form. Many of the opaque and metallic-looking specimens will still exhibit slight transparency and red color when backlit.

Pyrargyrite is light sensitive. Prolonged exposure to bright light will darken its transparency and cause it to become darker. Exposure also may cause a dark, dull film to form on crystal faces; this film can be removed by brushing a specimen with soap and water.

Pyrargyrite is very similar to Proustite, and forms a series with it. Pyrargyrite is the antimony-rich member, and Proustite is the arsenic-rich member. It is often not possible to visually distinguish these two minerals from each other. Pyrargyrite is the more common of this series, although good crystals of both these minerals are difficult to come across. Most good material in collections today are from closed, historical localities.

Pyrargyrite is named from the Greek words Pyr, "Fire" in allusion to the color of this mineral, and Argyros, meaning silver, describing its silver content.